Bryan C. Smith
It looks like in the EXCEPT function you are trying to return all the members of your Dim Client dimension's Dim Client hierarchy except the member with a key of 2. Is that correct
By executing the MEMBERS function against the hierarchy without specifiying the level, you will get the ALL member in your list. So, I would recommend using [Dim Client #].[Dim Client#].[Dim Client#].Members instead to return just the leaf level members and not the ALL level member.
Regarding the error, I don't know exactly what's going on with that. I would recommend creating the calculated member using the form- view of the Cube Designer's Calculations tab. This will help you get the overall syntax correct.
In the form view, you will need to give the calculated member a name, [HospVol]. (Be sure to include the brackets.)
You will need to identify it's parent hierarchy. In this case, select MEASURES.
Next, enter your expression: AGGREGATE(EXCEPT([Dim Client#].[Dim Client#].Members,[Dim Client#].[Dim Client#].&[2]),[Measures].[Item Qty])
Then, select your format string and visibility.
Finally, set the Non-Empty Behavior. This one is a little confusing but basically you identify a measure that when the measure is empty, the calculation is not performed. For this calculation, you can probably just ignore that.
Once you've set up the calculated member, just deploy your cube (you don't need to reprocess if the cube is already processed).
Good luck,
Bryan